北京理工大学

姓名：曹洁

职称：副教授

联系电话：010-68912667

电子邮箱：jcao@bit.edu.cn
 
学科专业：质谱分析

研究方向：

（1）无机配合物/有机化合物的结构研究；

（2）无机有机杂化超分子组装体的结构及性能；

（3）色谱/质谱法分离及识别手性化合物。

承担及作为主要学术骨干参加的科研项目：国家自然科学基金（21371025）；教育部留学回国基金（环糊精对盐酸司来吉兰手性药物的质谱研究）；教育部重点项目（手性药物分子识别的质谱研究）；973计划前期研究专项（大气中持久性有机污染物的污染成因研究）；中国科学院院长基金（伯胺类手性药物分子识别的质谱研究）；吉林省科技发展计划项目（大气中氯苯类持久性有机污染物的污染成因和对策探讨）等。

个人概况：

1986年、1989年获得南开大学学士和硕士学位，2001年获得加拿大渥太华大学博士学位。2000年11月至2002年4月加拿大渥太华大学从事博士后研究，2002年4月回国。2004年至2009年中国科学院研究生院从事手性药物色谱拆分的方法学研究及手性分子识别的质谱研究；2009年至今北京理工大学主要从事无机-有机超分子体系结构与性能的质谱研究。讲授过《分析化学》、《现代材料分析技术》、《生命分析化学》、《分析化学实验》、《近代仪器分析》、《现代化学专题讲座》、《有机结构分析》、《有机质谱原理及应用》、《色谱和光谱实验课》、《现代色谱质谱分析方法及实验》和《有机波谱分析》等本科生和研究生课程。曾获中国科学院研究生院优良课程奖、研究生院首批集中教学突出贡献奖和2008年中国科学院教学成果奖二等奖。发表SCI论文20余篇。

发表论文信息：

1.Y.X. Fan, Y. Zhang, Q.D. Jia, J. Cao*, W.J. Wu*. The stabilizing role of cyclodextrins on Keggin phsphotungstic acid by complexation unveiled by electrospraymass spectrometry. Mass Spectrom. Lett. 2015, 6(1), 13-16.

2. Q.D. Jia, Y. Zhang, J. Cao*. Characterization of polyoxometalates by electrospray ionization mass spectrometry. Sci. China Chem. 2015, 58(7):1206-1210.

3.Q.D. Jia, J. Cao*, Y.P. Duan and C.W. Hu*. The solution chemistry and reactivity of lacunary Keggin silicotungstates monitored in real-time by a combination of mass spectrometry and electrochemistry. Dalton Trans. 2015, 44, 553-559.

4.J. Cao*, C. Xu, Y.X. Fan, L.Y. Fan, X.H. Zhang* and C.W. Hu. Selective production of electrostatically-bound adducts of alkyl cations/polyoxoanions by the collision induced fragmentations of their quaternary ammonium counterparts. J. Am. Soc. Mass Spectrom. 2013, 24, 884-894.

5.J. Cao*, C.C Li, Z.X. Zhang, C. Xu, J. Yan, F.Y. Cui, C.W. Hu*. Intriguing role of a quaternary ammonium cation in the dissociation chemistry of Keggin polyoxometalate anions. J. Am. Soc. Mass Spectrom. 2012, 23, 366-374.

6.X.F. Wang, J. Cao, K.L. Huang, Y.Q. Xu, Y.N. Chi*, C.W. Hu*. A novel 3D coordination polymer from [HW7O24]5– stabilized by copper(II)-complex and sodium sations: structure, solid-state stability and aqueous solution behavior. Eur. J. Inorg. Chem. 2013, 1788-1792.

7.J. Cao*, R.F Xu, H. Tang, S.S. Tang, M.H. Cao*. Synthesis of monodispersed CMC-stabilized Fe–Cu bimetal nanoparticles for in situ reductive dechlorination of 1, 2, 4-trichlorobenzene. Sci. Total Environ. 2011, 409, 2336-2341.

8.X.M. Hu, Q. Chen, D. Zhou, J. Cao*, Y.J. He*, B.H. Han*. One-step preparation of fluorescent inorganic–organic hybrid material used for explosive sensing. Polym. Chem. 2011, 2, 1124-1128.

9.X.M. Hu, Q. Chen, J.X. Wang, Q.Y. Cheng, C.G. Yan, J. Cao*, Y.J. He*, B.H. Han*. Tetraphenylethylene-based glycoconjugate as a fluorescence “turn-on” sensor for cholera toxin. Chem. Asian J. 2011, 6, 2376-2381.

10.Q. Chen, Y. Cui, T.L. Zhang, J. Cao*, B.H. Han*. Fluorescent conjugated polyfluorene with pendant lactopyranosyl ligands for studies of Ca2+-mediated carbohydrate-carbohydrate interaction. Biomacromolecules, 2010, 11, 13-19.

11.Q. Yu, J. Cao*, T. Liu, Z.X. Wang*. Fluorescence-quenching of tryptophan ion-18-crown-6 complex. A different observation from its neutral counterpart. Chem. Res. Chinese U. 2009, 25(3), 362-367.

12.Q. Yu, J. Cao*, G. Lu, Z.X. Wang*. The role of central ion in the chiral recognition by taking phenylalanine as an example. Sci. China, Ser. B 2009, \52(8), 1136-1141.

13.徐冲, 范艳璇, 范琳媛, 曹洁*, 胡长文*. 质谱在多金属氧簇化学中的应用. 化学进展, 2013, 25(5), 809-820.

14.Q. Yu, J. Cao*. The role of central ion in the chiral recognition by taking phenylalanine as an example. Sci. China, Ser. B 2009, 52(8), 1136-1141.

15.Q. Yu, J. Cao*. Fluorescence-quenching of tryptophan ion-18-crown-6 complex. A different observation from its neutral counterpart. Chem. Res. Chinese U. 2009, 25(3), 362-367.

16.J. Cao, Y.P. Tu, W.X. Sun, J.L. Holmes*. The water-solvated methanol ion and its isomer: experiment and theory. Int. J. Mass Spectrom., 2003, 222, 41-48.

17.J. Cao, W.X. Sun, J.L. Holmes*. The ions CH6O+· and CH7O+. Int. J. Mass Spectrom. 2002, 217, 179-184.

18.J. Cao, J.L. Holmes*. The determination of proton affinities of secondary alcohols from the dissociations of proton-bound molecular trios. A new application of the kinetic method. Eur. J. Mass Spectrom. 2001, 7, 243-247.

19.J. Cao, C. Aubry, J.L. Holmes*. The proton affinities of simple amines: Activation entropies and their effect on the kinetic method for evaluating proton affinities. J. Phys. Chem. A 2000, 104, 10045-52.

20.J. Cao, J.L. Holmes*. The proton affinities of amino-alkanes. A test case for the kinetic method. Int. J. Mass Spectrom. 2000, 195/196, 525-532.