河北大学

河北大学化学与环境科学学院研究生导师段小勇介绍如下：

一、个人简介

段小勇，男，硕士研究生导师。2016年毕业于兰州大学化学化工学院功能有机国家重点实验室，获理学博士学位，师从韩丙教授，研究方向为自由基化学。2017年3月至2018年3月在新加坡南洋理工大学(NTU-SPMS-CBC)池永贵教授组从事博士后研究工作，研究方向为不对称有机小分子催化。并于同年9月被引

进至河北大学化学与环境科学学院工作。主要研究方向为自由基化学、不对称催化、有机合成方法学等，已在相关研究方向发表多篇高水平SCI论文。

联系方式：duanxy05@126.com，

实验室：河北大学本部逸夫楼715实验室。

欢迎对有机化学感兴趣的有志人士加入我们课题组!

二、主讲课程及研究方向

1.主讲课程：有机化学，大学化学，基础操作实验，大学化学实验，有机合成与表征实验。

2.研究方向：自由基化学，不对称催化，有机合成方法学，手性药物分子合成研究。

三、代表性论文

Publications prior joining HBU:

9. Catalytic asymmetric acetalization of carboxylic acids for access to chiral phthalidyl ester prodrugs.Yingguo Liu, Qiao Chen, Chengli Mou, Lutai Pan, Xiaoyong Duan, Xingkuan Chen, Hongzhong Chen, Yanli Zhao, Yunpeng Lu, Zhichao Jin, Yonggui Robin Chi*Nature Communications volume 10, Article

number: 1675 (2019, DOI:10.1038/s41467- 019-09445-x)(https://www.nature.com/articles/s41467-019-09445-x)

8. Hydrazonyl Radical-Participated Tandem Reaction: A Strategy for the Synthesis of Pyrazoline- Functionalized OxindolesXiao-Yong Duan, Xiu-Long Yang, Pan-Pan Jia, Man Zhang, and Bing Han*Org. Lett., 2015, 17, 6022–6025.(https://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b03003?

journalCode=orlef7&quickLinkVolume=17&quickLinkPage=6022&selectedTab=citation&volume=17)

7. N-heterocyclic carbene-catalyzed stereoselective annulations: An efficient strategy for the synthesis of chromeno [4, 3-b] pyrrolidine derivatives.Jing Qi*, Xiao-Yong Duan, Li-Li Cao, Wen-Ying WangAsian J. Org. Chem., 2015, 4, 1254 –1257.(https://onlinelibrary.wiley.com/doi/10.1002/ajoc.201500266)

6. Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl RadicalsXiao-Yong Duan, Neng-Neng Zhou, Ran Fang, Xiu-Long Yang, Wei Yu, and Bing Han*.Angew. Chem. Int. Ed., 2014, 53, 3158 –3162.(https://onlinelibrary.wiley.com/doi/10.1002/anie.201309918)

5. Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and TetrahydropyridazinesXiao-Yong Duan, Xiu-Long Yang, Ran Fang, Xie-Xue Peng, Wei Yu, and Bing Han*J. Org. Chem., 2013, 78, 10692-10704

://pubs.acs.org/doi/abs/10.1021/jo4016908?journalCode=joceah&quickLinkVolume=78&quickLinkPage=10692&selectedTab=citation&volume=78)

4. Oxime Radical Promoted Dioxygenation, Oxyamination, and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones.Bing Han*, Xiu-Long Yang, Ran Fang, Wei Yu, Chao Wang, Xiao-Yong Duan, Shuai LiuAngew. Chem. Int. Ed., 2012, 51, 8816.

(https://onlinelibrary.wiley.com/doi/10.1002/anie.201203799)

3. Efficient aerobic oxidative synthesis of 2-aryl quinazolines via benzyl C–H bond amination catalyzed by 4-hydroxy-TEMPOBing Han*, Chao Wang, Run-Feng Han, Wei Yu,* Xiao-Yong Duan, Ran Fang and Xiu-Long YangChem. Commun., 2011, 47, 7818-7820.

(https://pubs.rsc.org/en/content/articlelanding/2011/cc/c1cc12308d#!divAbstract)

2. Efficient aerobic oxidative dehydrogenation of dihydropyrimidinones and dihydropyrimidinesBing Han*, Run-Feng Han, Yu-Wei Ren, Xiao-Yong Duan, Yi-Chuan Xu, Wei ZhangTetrahedron 2011, 67, 5615–5620.(https://www.sciencedirect.com/science/article/pii/S0040402011007952)

1. Photoinduced Intramolecular Addition of 3-Acyl-2-haloindoles to AlkenesShen-Ci Lu, Xiao-Yong Duan, Zong-Jun Shi, Bing Li, Yu-Wei Ren, Wei Zhang*, Yong-Hui Zhang and Zhi-Feng TuOrg. Lett., 2009, 11, 3902–3905.(https://pubs.acs.org/doi/abs/10.1021/ol901498f?

journalCode=orlef7&quickLinkVolume=11&quickLinkPage=3902&selectedTab=citation&volume=11)

四、科研项目

1. 河北大学科研启动经费，801260201299，腙自由基参与的烯烃的官能团化研究，2018.11-2021.10;

2. 2019年河北省自然科学基金-青年科学基金项目，B2019201101，腙自由基参与的含氮杂环化合物的合成研究，2019.09-2022.08;

3. 2019年度河北省引进留学人员资助项目，C20190503，杂原子自由基参与的杂环化合物的对映选择性合成, 2019.08-2022.07;